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A while ago I made this exact post talking about which characters of the show fits into the main position of the episodes? Who does the episodes mainly focus on? Well, since then I updated, and I decided to make a new one. It features the Mane Six, Spike, the CMCs, Big Mac, Discord, and Starlight. Special thanks to Ralli for the list template!

Characters S Episodes
Twilight Sparkle 1 Friendship is Magic, part 1, The Ticket Master, Boast Busters, Winter Wrap Up, Feeling Pinkie Keen (with Pinkie)
2 Lesson Zero, Luna Eclipsed, It's About Time, A Canterlot Wedding - Part 1, A Canterlot Wedding - Part 2
3 The Crystal Empire - Part 1, The Crystal Empire - Part 2, Magic Duel
4 Princess Twilight Sparkle - Part 1, Princess Twilight Sparkle - Part 2, Three's A Crowd (with Discord), Twilight Time (with the CMCs), Testing Testing 1, 2, 3 (with Rainbow), Twilight's Kingdom - Part 1 (with Discord), Twilight's Kingdom - Part 2 (with Discord)
5 Amending Fences, What About Discord? (with Discord), The Hooffields and McColts (with Fluttershy), The Cutie Re-Mark - Part 1 (with Starlight), The Cutie Re-Mark - Part 2 (with Starlight)
6 No Second Prances (with Starlight), P.P.O.V. (Pony Point of View) (with AJ, Pinkie, and Rarity), Top Bolt (with Rainbow)
7 Celestial Advice (with Starlight), A Flurry of Emotions, Once Upon a Zeppelin
Applejack 1 Applebuck Season, Look Before You Sleep (with Rarity), Fall Weather Friends (with Rainbow)
2 The Last Roundup, The Super Speedy Cider Squeezy 6000
3 Apple Family Reunion, Spike at Your Service (with Spike)
4 Bats! (with Fluttershy), Pinkie Apple Pie (with Pinkie), Simple Ways (with Rarity), Somepony to Watch Over Me (with Apple Bloom), Leap of Faith
5 Made in Manehattan (with Rarity), Hearthbreakers (with Pinkie), The Mane Attraction
6 Applejack's "Day" Off (with Rarity), The Cart Before the Ponies (with Rainbow, Rarity, and CMCs), Buckball Season (with Pinkie, Rainbow, and Fluttershy), Viva Las Pegasus (with Fluttershy), PPOV (with Twilight, Pinkie, and Rarity), Where the Apple Lies (with Big Mac)
7 Honest Apple (with Rarity), The Perfect Pear, Campfire Tales (with Rainbow, Rarity, and CMCs)
Pinkie Pie 1 Griffon the Brush Off (with Rainbow), Swarm of the Century, Feeling Pinkie Keen (with Twilight), Party of One
2 Baby Cakes, A Friend in Deed, MMMystery on the Friendship Express
3 Too Many Pinkie Pies
4 Pinkie Apple Pie (with Applejack), Pinkie Pride, Maud Pie
5 The Lost Treasure of Griffonstone (with Rainbow), Party Pooped, The One Where Pinkie Pie Knows, Hearthbreakers (with Applejack)
6 The Gift of the Maud Pie (with Rarity), Spice Up Your Life (with Rarity), Buckball Season (with Applejack, Rainbow, and Fluttershy), PPOV (with Twilight, AJ, and Rarity)
7 Rock Solid Friendship, Not Asking for Trouble, Daring Done (with Rainbow), Secrets and Pies (with Rainbow)
Fluttershy 1 Dragonshy, Stare Master (with the CMCs), Green Isn't Your Color (with Rarity), A Bird in the Hoof
2 Putting Your Hoof Down, Hurricane Fluttershy
3 Keep Calm and Flutter On (with Discord)
4 Bats! (with Applejack), Filli Vanilli, It Ain't Easy Being Breezies
5 Make New Friends but Keep Discord (with Discord), Scare Master, The Hooffields and McColts (with Twilight)
6 Flutter Brutter, Buckball Season (with Applejack, Pinkie, and Rainbow), Viva Las Pegasus (with Applejack)
7 Fluttershy Leans In, Discordant Harmony (with Discord), A Health of Information
Rarity 1 Look Before You Sleep (with Applejack), Suited For Success, A Dog and Pony Show (with Spike), Green Isn't Your Color (with Fluttershy)
2 Sisterhooves Social (with Sweetie Belle), Sweet and Elite
4 Rarity Takes Manehattan, Simple Ways (with Applejack), Inspiration Manifestation (with Spike)
5 Canterlot Boutique, Rarity Investigates! (with Rainbow), Made in Manehattan (with Applejack)
6 The Gift of the Maud Pie (with Pinkie), The Saddle Row Review, Applejack's "Day" Off (with Applejack), Spice Up Your Life (with Pinkie), The Cart Before the Ponies (with Applejack, Rainbow, and CMCs), PPOV (with Twilight, AJ, and Pinkie)
7 Forever Filly (with Sweetie Belle), Honest Apple (with AJ), Campfire Tales (with Rainbow, Rarity, and CMCs), It Isn't the Mane Thing About You
Rainbow Dash 1 Griffon the Brush Off (with Pinkie), Fall Weather Friends (with Applejack), Sonic Rainboom
2 May the Best Pet Win!, The Mysterious Mare Do Well, Read It and Weep
3 Sleepless in Ponyville (with Scootaloo), Wonderbolts Academy
4 Daring Don't, Rainbow Falls, Testing Testing 1, 2, 3 (with Twilight)
5 Tanks for the Memories, The Lost Treasure of Griffonstone (with Pinkie), Rarity Investigates! (with Rarity)
6 Newbie Dash, Stranger Than Fan Fiction, The Cart Before the Ponies (with Rarity, Applejack, and CMCs), 28 Pranks Later, Buckball Season (with Applejack, Pinkie, and Fluttershy), Top Bolt (with Twilight)
7 Parental Glideance (with Scootaloo), Campfire Tales (with Rainbow, Rarity, and CMCs), Daring Done (with Pinkie), Secrets and Pies (with Pinkie)
Mane Six 1 Friendship is Magic, part 2, Bridle Gossip (with Apple Bloom), Over a Barrel, The Cutie Mark Chronicles (with the CMCs), The Best Night Ever
2 The Return of Harmony Part 1 (with Discord), The Return of Harmony Part 2 (with Discord), Hearth's Warming Eve
3 Games Ponies Play, Magical Mystery Cure
4 Castle Mane-ia, Power Ponies (with Spike), Trade Ya!
5 The Cutie Map - Part 1 (with Starlight), The Cutie Map - Part 2 (with Starlight), Castle Sweet Castle, Do Princesses Dream of Magic Sheep?
6 A Hearth's Warming Tail (with Starlight), Every Little Thing She Does (with Starlight)
7 Fame and Misfortune, Shadow Play, Part I, Shadow Play, Part II
Spike 1 A Dog and Pony Show (with Rarity), Owl's Well That Ends Well
2 Secret of My Excess, Dragon Quest
3 Spike at Your Service (with Applejack), Just for Sidekicks
4 Power Ponies (with the Mane Six), Inspiration Manifestation (with Rarity), Equestria Games
5 Princess Spike
6 Gauntlet of Fire, The Times They Are a Changeling, Dungeons & Discords (with Discord and Big Mac)
7 Triple Threat, Uncommon Bond
Apple Bloom 1 Bridle Gossip (with the Mane Six), Call of the Cutie
2 The Cutie Pox, Family Appreciation Day
4 Somepony to Watch Over Me (with Applejack)
5 Bloom & Gloom, Brotherhooves Social (with Big Mac)
6 On Your Marks
Sweetie Belle 2 Sisterhooves Social (with Rarity)
4 For Whom the Sweetie Belle Toils
7 Forever Filly (with Rarity)
Scootaloo 3 Sleepless in Ponyville (with Rainbow)
4 Flight to the Finish
7 Parental Glideance (with Rainbow)
Cutie Mark Crusaders 1 Stare Master (with Fluttershy), The Show Stoppers, The Cutie Mark Chronicles (with the Mane Six)
2 Hearts and Hooves Day (with Big Mac), Ponyville Confidential
3 One Bad Apple
4 Twilight Time (with Twilight)
5 Appleoosa's Most Wanted, Crusaders of the Lost Mark
6 The Cart Before the Ponies (with Applejack, Rainbow, and Rarity), The Fault in Our Cutie Marks
7 Hard to Say Anything (with Big Mac), Campfire Tales (with Rainbow, Rarity, and CMCs)
Big McIntosh 2 Hearts and Hooves Day (with CMCs)
5 Brotherhooves Social (with Apple Bloom)
6 Dungeons & Discords (with Spike and Discord), Where the Apple Lies (with Applejack)
7 Hard to Say Anything (with CMCs)
Discord 2 The Return of Harmony Part 1 (with the Mane Six), The Return of Harmony Part 2 (with the Mane Six)
3 Keep Calm and Flutter On (with Fluttershy)
4 Three's A Crowd (with Twilight), Twilight's Kingdom - Part 1 (with Twilight), Twilight's Kingdom - Part 2 (with Twilight)
5 Make New Friends but Keep Discord (with Fluttershy), What About Discord? (with Twilight)
6 Dungeons & Discords (with Spike and Big Mac)
7 Discordant Harmony (Fluttershy)
Starlight Glimmer 5 The Cutie Map - Part 1 (with the Mane Six), The Cutie Map - Part 2 (with the Mane Six), The Cutie Re-Mark - Part 1 (with Twilight), The Cutie Re-Mark - Part 2 (with Twilight)
6 The Crystalling - Part 1, The Crystalling - Part 2, No Second Prances (with Twilight), A Hearth's Warming Tail (with Mane Six), Every Little Thing She Does (with Mane Six), To Where and Back Again - Part 1, To Where and Back Again - Part 2
7 Celestial Advice (with Twilight), All Bottled Up, A Royal Problem, To Change a Changeling
Other 5 Slice of Life

Updates as the seasons progress. The shortcut to this page will be on my page.

You have any opinions of your own on who's the main character(s) for each episode?